Case Report: Forensic Chemistry Analysis in Asbestos Litigation

Authors

DOI:

https://doi.org/10.17063/bjfs12(3)y2024264-273

Keywords:

forensic chemistry, chrysotile asbestos, FTIR, espectroscopia Raman, SEM-EDS, XRD, XRF

Abstract

Chrysotile asbestos, a naturally occurring fibrous silicate mineral, is extensively used in various industries due to its advantageous properties, including low cost, thermal insulation, mechanical strength, and resistance to chemical and biological degradation. However, its usage is associated with significant health risks, including mesothelioma and lung cancer, and environmental concerns due to its slow degradation and widespread contamination. Despite legislative efforts, asbestos remains a prevalent issue, particularly in countries like Brazil with significant asbestos deposits. Legislation addressing chrysotile asbestos has led to its prohibition in many countries, including Brazil. In forensic chemistry, the identification of materials suspected of containing asbestos is crucial for compliance with regulations. This study aims to showcase chemical and physical analyses conducted on samples from a real investigation involving a metallurgical company accused of using asbestos-containing materials. Various analytical techniques, including FTIR, Raman spectroscopy, SEM-EDS, XRF, and XRD, were employed, consistently identifying chrysotile asbestos in the samples despite its banishment. This case underscores the importance of forensic chemistry in identifying hazardous materials and ensuring compliance with regulatory standards.

References

Peña-Castro M, Montero-Acosta M, Saba M. A critical review of asbestos concentrations in water and air, according to exposure sources. Heliyon. 2023;9:e15730.

https://doi.org/10.1016/j.heliyon.2023.e15730

Miao X, Yao T, Dong C, Chen Z, Wei W, Shi Z, et al. Global, regional, and national burden of non-communicable diseases attributable to occupational asbestos exposure 1990-2019 and prediction to 2035: worsening or improving? BMC Public Health. 2024;24:1-15.

https://doi.org/10.1186/s12889-024-18099-4

Araújo CA. O amianto crisotila e o desenvolvimento sustentável do brasil [dissertation]. Goiânia: Pontifícia Universidade Católica de Goiás (PUC Goiás); 2011.

Scliar C. Amianto. Mineral mágico ou maldito? Ecologia humana e disputa político-econômica. Belo Horizonte: CDI; 1998.

Brasil. Ministério do Trabalho e Emprego. Norma Regulamentadora no 15 (NR-15) - Atividades e operações insalubres - anexo no 12 - Limites de tolerância para poeiras minerais. Portaria SSST n.º 01, de 28 de maio de 1991.

Rossi A. De proteção contra substância cancerígena a "demissão em massa", os efeitos da proibição do amianto [Internet]. São Paulo: BBC News Brasil. 2017 Nov 29 [cited 2024 May 1]. Available from: https://www.bbc.com/portuguese/brasil-42175321.

de Souza DM, Schnitzler DC. Avaliação da presença de amianto do tipo crisotila em caixas d'água de fibrocimento [Internet]. Pato Branco: Universidade Tecnológica Federal do Paraná; 2019 [cited 2024 May 1]. Available from: file:///C:/Users/maria/Downloads/4753-21943-1-PB.pdf

Kusiorowski R, Gerle A, Kujawa M, Antonovič V, Boris R. Structural Characterisation of End-of-Life Cement-Asbestos Materials from Lithuania. Fibers. 2024;12:37. https://doi.org/10.3390/fib12040037

Instituto Nacional de Câncer - INCA. STF mantém proibição do uso de amianto crisotila no Brasil - Fibra mineral está associada a diversas doenças, inclusive o câncer [Internet]; 2023. [cited 2024 May 1]. Available from: https://www.gov.br/inca/pt-br/assuntos/noticias/2023/stf-mantem-proibicao-do-uso-de-amianto-crisotila-no-brasil.

Jovanovski G, Makreski P. Minerals from Macedonia. XXX. Complementary use of vibrational spectroscopy and X-ray powder diffraction for spectra-structural study of some cyclo-, phyllo- and tectosilicate minerals - A review. Macedonian Journal of Chemistry and Chemical Engineering 2016;35:125. https://doi.org/10.20450/mjcce.2016.1047

Vortisch W, Baur X. Asbestiform antigorite: A dangerous mineral in serpentinites. A plea to treat asbestiform antigorite as an asbestos group mineral in terms of its occupational health safety effects. Neues Jahrbuch Fur Mineralogie- Abhandlungen 2018;195:41.

https://doi.org/10.1127/njma/2017/0070

Essih S, Pardo L, Cecilia JA, dos Santos-Gómez L, Colodrero, RMP, Pozo M, et. all. Microwave-assisted acid treatment for the mineral transformation of chrysotile as an alternative for asbestos waste management. Environ Geochem Health. 2024;46:332.

https://doi.org/10.1007/s10653-024-01993-6

Published

2024-12-31

How to Cite

Lima Logrado, L. P., Tadão Joko, C., & Lima Logrado, A. (2024). Case Report: Forensic Chemistry Analysis in Asbestos Litigation. Brazilian Journal of Forensic Sciences, Medical Law and Bioethics, 12(3), 264–273. https://doi.org/10.17063/bjfs12(3)y2024264-273

Issue

Section

Estudo de Caso